Grisaille is a method I stumbled upon while painting this portrait of John. I started by painting the first layer in sepia. That is, the whole painting, the correct values, in sepia. Then I let it completely dry and layered in alizarin crimson, yellow ochre, and pthalo blue for the shadow areas.
Grisaille is a technique used by the old masters. "Gris" means grey. The underpainting, or drawing, can be grey or any neutral color.
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